Method of protecting well apparatus against contamination during handling

ABSTRACT

A method of protecting downhole well apparatus having openings therein or movable parts during handling of such apparatus, particularly during positioning thereof in a wellbore, comprising; filling the openings or coating the movable parts with a blend of a wax and a polymer, handling the so-treated apparatus such as positioning the same in a wellbore, and removing the filling or coating blend from the openings or movable parts.

United States Patent [191 Sparlin et al.

[4 1 Sept. 16, 1975 METHOD OF PROTECTING WELL APPARATUS AGAINST CONTAMINATION DURING HANDLING [75] Inventors: Derry D. Sparlin; Clarence B. Kolb,

Jr., both of Ponca City, Okla.

[73] Assignee: Continental Oil Company, Ponca City, Okla.

[22] Filed: May 1, 1974 [21] Appl. No.: 465,977

[52] US. Cl 166/296; 166/315 [51] Int. Cl. E21B 43/10 [58] Field of Search 166/296, 295, 294, 280

[56] References Cited UNITED STATES PATENTS 10/1962 Mallinger 166/296 X 8/1966 Brandt 166/296 X 3,273,641 9/1966 Boume 166/296 X 3,302,719 2/1967 Fischer 166/280 3,316,965 5/1967 Watanabe... 166/295 X 3,333,635 8/1967 Crawford 166/296 X Primary E)raminerStephen J. Novosad Attorney; Agent, or FirmRichard W. Collins ABSTRACT 5 Claims, No Drawings METHOD OF PROTECTING WELL APPARATUS, AGAINST CONTAMINATION DURING HANDLING BACKGROUND OF THE Manag a Field of thelnvention r This invention relates to apparatus and'methodsfor completing wells. More particularly',rit relates to such downhole some type of apparatusthrough'which fluids are passed between the .wellbore and the surrounding formation. Suchapparatus include perforated liners,

screens, packers and the 'like. One characteristic of i such apparatus isxthat they have cavities or-.recesses such as an opening or openingstherethrough through which the fluid'passes. The size-of the openings mayvary considerably: depending on 1 the exact nature and intended use of the apparatus. Otherapparatus have movable parts whichmust be activated once the"appa-= ratus has been positioned downhole. Such apparatus include packers'which have jaws which, once r'the packer is positioned downhole; must be moved out to contact andbite intothe surrounding casingorborehole wall. Such apparatus are handled "repeatedly'from the time they -.are manufactured until theyjare in'posi- '2 *lt isran obje'ct of this invention to provide an improved apparatus and method for positioning-downhole in -a Well aw-apparatus having openings ther'ethrough or movable partsi lt' isa further'object tospjrovide'suchan apparatus fand' method where-in the openings are I plugged or movable parts coat'e'd with 2 a removable andlin'gand positioning pluggingf material durin'g the of the apparatus? It is a still'furtherobject-to provide such aremovable plugging material having*improvecljbonding to'theap I Paratus:*'-- it-is another object ='toprov-ide an organicv removable plugging materiaiwnieh'is harder than previously used organic" materials It is s'till'another object to provide such-an organic" removable plug ing material which melts 'at a temperature lower than that of the borehole in which his positioned-'or-can be removed from t'he'opening's' or-movableparts 'by'c'ontacting' the same with a'solventf tion downhole" in awell ready for-use.-'Such handling includes packaging, shipping, unpackaginggstoring and a positioning in awell. The, apparatus are positioned downhole in a well by lowering the same through a borehole, such as via a wireline or as a part of the tubing string, to the desired position: downhole. The borehole through which the apparatus is lowered may be an open hole or may be ca sed. During its passage through the borehole the apparatus necessarily contacts and passes through any fluid or'detritus which rnay be inf the wellbore and can scrape against the sidesof the case d or open borehole, especially if the pisre'hoie deviates from the vertical. Throughout the handling'a nd positioning operations there are many opportunities foreitmaterial prior to positioning the apparatus downhole.

After the apparatus is positioned, the plugging material melts away or is othewise removed to clear the openings or leave the movable parts free of extraneous materials. Previously known plugging or coating materials include inorganic solids such as hydrated nitrates of chromium, iron, mercury nickel; pure'organid compounds such as various acids, and crudeorganic materials such as paraffin, 'gillsonit, beeswax, metals and metallic alloys. 1 .1.

. throughthe borehole-but which are moved out into 1" Othe r-objects,-' advantages and featuresfo f the invention will 'bertor'neapparentfrom a consideration of the following specificatidna'hd appe'hded claims. I

BRIEFSUMMABYOFIHE INMENTION A rri'e'thod'ofprotectirigand maintainihg open caviti'e'so'r recess'e's such openings in or indvabl'e parts of apparatus" during placetnerifof such alppafa tus down hole in a well comprising: (aifillirig the cavitiesof the apparatus with able n'do a wax and a polymer, and b) positioning-"the apparatusdo'wiiliole in a well. If'the tmpe'r'atur'bf the borehole at the downholelocation is higher rhahthe melting pointof the 'wa'x polynier blend, the well is'shiit in until 'the blend melts. Alterna may oFirthe temperature *o the borehole is lower than the rrielting'fpoint of the" blend, hot oil oi oth'er. sol veiit fort he blend is flowed through ithe apparatusg' DESCRIPTION OF THE PREFERRED A w ;LEMBODIMENT I M'anytype's of liners andscreens have been usedtfor years its riont'if oi 'production of unconsolidated forma-' tion sari d 6n; and water wells. (iorhrnon typje'sof l ners'cdns'ist of tubingin; which s lqtjs orfothfer'holes of various 'siies and gonfiguration s "are cut'.' w'n fluids can passifrom the foi'inatjio 'o ugh"th'e slots 'into the tab the we ll, out sand or other f Sl t? and e mehe, nor. Modifications or wrapping the exterior formation particies br idge e rq i P m th u h these liners be e, as", of the liner with v t spaced at regular intervals. Anotherf 'modification i s a liner having the openings 'i'nsit coated onlthe exterior thereof by a permeable solid material such as plastic coated sand or concrete. Such permeable coating acts as the filter media and the liner itself acts as a base or form to support the permeable coating. The process of this invention can 'becarried out usinganyiof these liners and screens.

Similarly the invention may be carried out using any downhole'apparat us which contains a part or element which must bemoved in relation to other parts or elements once the apparatus is positioned downhole. Typical are packers which contain jaw members which are in a contracted position during passage of the packer contact with the borehole sidewall once the packer has .b een lowered to its desired location. Such apparatus have cavities or recesses between the moving parts and the stationaryparts.

The temporary plugging or blocking-material of this invention is a blend of a wax and a polymer. It has been found that wax alone does notadhere well to the metal surfaces of the cavities which are to be plugged. Also wax alone has too low a softening point comparedto its melting point. This means that with an apparatus being positioned, which apparatus contains cavities filled with wax, the wax softens before the apparatus reaches its final location. This premature softening may result in the wax acutally attracting and picking up undesired solid plugging material and holding the same in the cavity area. Addition of a polymer to the wax forms a blend having a softening point which is desirably close to the melting point and which bonds better to metal than. wax alone. Approximately equal weights of wax and polymer are preferred. As little as 20 percent by weight polymer imparts a substantial increase in softening point. More than about 75 percent by weight polymer results in a blend with a softening point and melting point which aretoo high for most applications.

The wax is preferably a synthetic paraffin wax having a softening point not substantially below its melting point. The polymer may be a solid polyvinyl acetate, a

polyolefin such as a polyethylene, a polyamide, a rosintype polymer such as a rosin ester, for example a glycerol ester of rosin or a synthetic polyterpene.

The softening point of the blend should preferably be within 10 to 15 of its melting point. The melting point of the blend should be a temperature above ambient temperature and equal to or slightly less than the temperature at which the apparatus which is coated with the blend can be heated during use. In well operations the melting point should be greater than the surface temperature but equal to or less than the temperature of the borehole in which a coated apparatus is positioned.

A series of tests were made to determine the strength with which wax and wax-polymer blends adhered to metal. The metal used was two rectangular mild steel specimens 3/16 inch by 1 inch by 2 A inch. Each specimen weighed approximately 24 grams. Various waxes and wax-polymer blends were heated to above their melting point and while still hot painted with a paint brush onto a 1 square inch surface area on one side at the end of each specimen. The coated areas of the two strips were then pressed together and held until the coating cooled and solidified. The joined strips were then vertically suspended by one end in an oven. The temperature was slowly raised and the temperature at which one strip fell away from the other strip was noted. This was taken as the softening point.

inch outside FEATHER slotted liner having an inside diameter of 5 inches. The section contained l8slots uniformly positioned around its lateral sidewall. Each slot was 2 inches long, Vs inch wide at the interior of the liner and feathering to V2 inch wide at the outside of the liner. The liner was typical of those used in producing wells in California which produce sand along with the well fluids. A blend of 50 parts by weight paraffin wax D and 50 parts by weight synthetic polyterpene was mixed together at a temperature of 220F and applied while hot by a paint brush to the slots of the liner until all the slots were filled. The coated liner was allowed to come to room temperature. The waxpolymer blend hardened-and adhered strongly to the slot sidewalls. The coated liner was placed in an oven and observed as the temperature was slowly increased. The blend began to melt at 215F. After 1.5 hours additional heating, the wax-polymer blend had all melted and completely run out of the slots leaving them open. The temperature of the oven had risen to 220F.

This test proved that the wax-polymer blend could be satisfactorily placed in the slots of a liner and harden so that no extraneous solid material could enter the slot. When the liner was heated to above the melting point of the blend, the blend completely ran out of the slots freeing the liner for use in passing fluids.

A sample of the above wax-polymer blend was mixed with a typical California crude oil. The blend was completely soluble in the oil at a temperature of 180F. Similar results were obtained with diesel fuel, kerosene and xylene in place of crude oil. These tests indicate that wax-polymer blend can be removed at a temperature lower than the melting point of the blend by the use of a solvent such as crude oil, diesel fuel, kerosene or xylene.

WELL EXAMPLE A well in the San Miguelito Field of California was drilled through an oil and gas pay zone extending from 12,780 feet to 13,265 feet. Since other wells in the field were known to have sand problems, a slotted liner was positioned opposite the pay zone and the well placed on production. After six months on production the well casing collapsed. This was believed due to sand being produced through the liner along with the gas and oil causing the formation sand to shift and exert sufficient pressure against the casing to collapse it. The liner was pulled from the hole and examined. Some of the slots were eroded. It was postulated that most of the slots had become plugged while the liner was originally being placed in the hole. Thus all production had occured through the few remaining unplugged holes. The

Wax Polymer Melting Point* Steel Specimens Example 1 part by weight) 1 part by weight) (F.) Separated (Softening PointF) l Paraffin Wax A none 146 153 129 2 Paraffin Wax A Synthetic polytcrpene 134 3 Paraffin Wax B none 147 4 Paraffin Wax 13 Synthetic polytcrpcnc 165 163 5 Parafiin Wax C none 201) 158 6 Paraffin Wax C Synthetic polyterpcnc 201) 210 210 *ASTM D127 The foregoing tests show that addition of a polymer to the wax raised the softening point close to the melting point.

A test was made using a 2 foot long section of a 5 V2 high flow rate through these few holes caused the holes to be eroded by the loose formation sand which was produced along with the oil. The bottom of the well was then redrilled through the producing interval. The estimated bottom hole circulating temperature of this well was 210F.

Seventeen 30 foot long sections of 2 /s inch diameter pipe was perforated with twenty A inch diameter holes per foot. A wax-polymer blend was prepared by mixing together 50 pounds of parafiin wax having a melting point of 200F and a softening point of 158F and 50 pounds of a synthetic polyterpene polymer and heating to 2 10F. The blend softened and melted at 201F. The melt was applied to the liner sections by brushing a sufficient quantity into the holes to fill the holes. The blend hardened when it cooled below 201F. The liner was made up by coupling the seventeen sections together as the liner was run into the open hole at the bottom of the casing. The liner was positioned opposite the pay zone. The well was returned to production and produced at the same rate, 200 barrels oil per day, as before placement of the liner but at a decreased pressure drop. No sand was produced. Six months after placement of the liner the well was still producing satisfactorily with no sand problems. These results indicate that the wax-polymer blend stayed in the liner openings throughout the placement of the liner and kept sand from entering the openings during placement. The high production rate indicates that the wax-polymer blend melted and ran out of the liner openings when the liner reached the pay zone which had a temperature above the melting point of the blend. The decreased pressure drop indicates that a large number of liner openings were open and available for fluid production.

What is claimed is: 1. A method of placing a cavitycontaining well apparatus downhole in a wellbore comprising:

a. blending together from 25 to 80 parts by weight of a paraffin wax heated to a temperature above its melting point and from to 20 parts by weight of a polymer selected from the class consisting of polyterpenes, polyvinyl acetates, polyolefins, polyamides and rosin esters to form a melted waxpolymer blend having a softening point l0-l5F below its melting point,

b. filling the cavity of the well apparatus with the melted wax-polymer blend,

c. solidifying the wax-polymer blend,

(1. positioning the so-treated well apparatus downhole in a wellbore, and

e. removing the wax-polymer blend from the cavity.

2. The method of claim 1 wherein the cavity is filled by brushing the melted blend into the cavity.

3. The method of claim 1 wherein the blend is solidified by allowing the blend to cool to ambient temperature.

4. The method of claim 1 wherein the apparatus is a screen, slotted liner or packer.

5. The method of claim 1 wherein the blend is removed from the cavity by contacting the blend with a solvent selected from the group consisting of crude oil,

diesel fuel, kerosene or xylene. 

1. A METHOD OF PLACING A CAVITYCONTAINING WELL APPARATUS DOWNHOLE IN A WELLBORE COMPRISING: A. BLENDING TOGETHER FROM 25 TO 80 PARTS BY WEIGHT OF A PARAFFIN WAX HEATED TO A TEMPERATURE ABOVE ITS MELTING POINT AND FROM 75 TO 20 PARTS BY WEIGHT OF A POLYMER SELECTED FROM THE CLASS CONSISTING OF POLYTERPENES, POLYVINYL ACETATES, POLYOLEFINS, POLYAMIDES AND ROSIN ESTERS TO FROM THE MELTED WAX-POLYMER BLEND HAVING A SOFTENING POINT 10-15*F BELOW ITS MELTING POINT, B. FILLING THE CAVITY OF THE WELL APPARATUS WITH THE MELTED WAX-POLYMER BLEND, C. SOLIDFYING THE WAX-POLYMER BLEND, D. POSITIONING THE SO-TREATED WELL APPARATUS DOWNHOLE IN A WELLBORE, AND E. REMOVING THE WAX-POLYMER BLEND FROM THE CAVITY.
 2. The method of claim 1 wherein the cavity is filled by brushing the melted blend into the cavity.
 3. The method of claim 1 wherein the blend is solidified by allowing the blend to cool to ambient temperature.
 4. The method of claim 1 wherein the apparatus is a screen, slotted liner or packer.
 5. The method of claim 1 wherein the blend is removed from the cavity by contacting the blend with a solvent selected from the group consisting of crude oil, diesel fuel, kerosene or xylene. 